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1.
《International Journal of Hydrogen Energy》2022,47(81):34387-34396
This work develops a novel magnetic photocatalysts ZnO/SrFe12O19 (ZS) synthesized with hydrothermal process. The introduction of SrFe12O19 not only enhances the photocatalytic behavior of ZnO towards Rhodamine B (RhB) decomposition, but also reinforces the recycling stability. Especially, ZS-5 composite exhibits the optimal photocatalytic performance, and the RhB decomposition reaches 99.5% after being exposed to simulative sunlight for 70 min, which is obviously superior to that of bare ZnO. Furthermore, the ZS-5 can be recovered from RhB solution by an extra magnet space and reused. After five recycles, the RhB removal efficiency can still be maintained over 90%. Such prominent photocatalytic property and stability of ZS-5 are associated with the greatly improved detachment efficiency of photoexcited carriers in a magnetic field. This study could provide a new-type recyclable photocatalyst that can effectively purify dye wastewater for convenient recovery. 相似文献
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《Ceramics International》2022,48(20):29959-29966
High-purity SiC ceramic devices are applied in semiconductor industry owing to their outstanding properties. Nevertheless, it is difficult to densify SiC ceramics without any sintering additive even by HP sintering. In this work, high-purity and dense SiC ceramics were fabricated by HP sintering with very low amounts of sintering aids. Residual B content was only 556 ppm and relative density was more than 99.5%. Furthermore, thermal conductivity of as-prepared SiC ceramics was improved from 155 W m?1 K?1 to 167 W m?1 K?1 by increasing holding time and their plasma corrosion resistance was promoted in the meantime. The as-prepared high-purity SiC ceramics have broad application prospects in the field of semiconductor industry. 相似文献
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根据水泥烧成热耗的组成,降低高温设备表面散热是降低水泥烧成热耗的重要途径之一,而减少高温窑炉墙壁的热传导可有效降低设备的表面散热。本文在介绍无机内保温涂层隔热原理的基础上,对保温涂层的应用效果进行了对比研究,通过在传统耐火隔热材料的基础上增加新型无机内保温涂层,可有效降低高温设备外表面温度,减少水泥生产中的散热损失,达到节能降耗的目的。 相似文献
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针对常见泥石流防治结构被冲击破坏的问题,基于“柔性消能”理念,结合张弦梁结构和竖向预应力锚杆技术,提出一种既能改善结构受力性能、增加结构整体抗冲击能力、保证结构安全可靠,又能减小结构构件截面尺寸、节约成本、便于现场施工组装和后期运营维护的新型地锚张弦梁式泥石流格栅坝,并阐述其技术原理。根据泥石流荷载分布和新型地锚张弦梁式泥石流格栅坝的受力特征,给出其简化的内力计算方法;并利用SAP2000建立新结构有限元模型,分析了结构的整体受力,验证了构件简化计算方法的合理性;结合Python语言和Qt De? signer软件开发了相应的设计计算软件,对新型地锚张弦梁式泥石流格栅坝的内力进行求解。结果表明:提出的新结构抗冲击性能好,构件受力均匀;以后设计中应关注竖杆的剪切脆性破坏和立柱偏心受力情况,保证结构安全;变形协调仅使底层张弦梁与竖杆内力偏大,实际工程应用时,应着重验算底层构件,防止其破坏;文中提出的简化计算方法能较准确的反映结构的受力特性,具有一定的合理性,研究可为新型地锚张弦梁式泥石流格栅坝的设计计算和推广应用提供理论依据和技术支持。 相似文献
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Yujie Chen Yiping Song Zhen Zhang Yali Chen Qiliang Deng Shuo Wang 《Advanced functional materials》2021,31(41):2104885
Various products, including foods and pharmaceuticals, are sensitive to temperature fluctuations. Thus, temperature monitoring during production, transportation, and storage is critical. Facile indicators are required to monitor temperature conditions via color changes in real time. This study aimed to prepare and apply thiol-functionalized covalent organic frameworks (COFs) as a novel indicator for monitoring thermal history and temperature abuse. The COFs underwent obvious color changes from bright yellow to purple after exposure to different temperatures for varying durations. The reaction kinetics are analyzed under isothermal conditions, which reveal that the order of reaction rates is k−20°C < k4°C < k20°C < k35°C < k55°C. The activation energy (Ea) of the COFs is calculated using the Arrhenius equation as 50.71 kJ moL−1. The COFs are capable of sensitive color changes and offer a broad temperature tracking range, thereby demonstrating their application potential for the monitoring of temperature and time exposure history during production, transportation, and storage. This excellent performance thermal history indicator also shows promise for expanding the application field of COFs. 相似文献
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Xiao-Mei Sha Li-Jun Zhang Wen-Mei Chen Guang-Yao Wang Jin-Lin Li Zi-Zi Hu Zong-Cai Tu 《International Journal of Food Science & Technology》2022,57(3):1573-1586
Thermal action in extraction process had effects on characteristic tryptic peptides identification and gelling properties of porcine gelatin. SDS-PAGE, HPLC-LTQ/Orbitrap high-resolution mass spectrometry, texture analyser and rheometer were used to evaluate collagen depolymerisation degree, characteristic tryptic peptides and gelling properties of gelatins prepared in various thermal actions. Results showed that with increasing temperature and time, depolymerisation degree enlarged, while gel strength, gelling and melting temperature decreased. Mass spectra showed that 47 and 49 common characteristic tryptic peptides were identified in gelatins extracted at 50 °C and 100 °C with various times, respectively. Moreover, 34 common characteristic tryptic peptides were identified in all gelatin samples. Further comparison between this work and our previous investigations yielded 20 common characteristic tryptic peptides, which stably exist in various thermal actions. These common characteristic tryptic peptides may be very helpful for the accurate authentication of porcine gelatin. 相似文献
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